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Royal Society of Chemistry, Chemical Communications, 18(51), p. 3754-3757

DOI: 10.1039/c5cc00453e

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Enantio-Enriched CPL-active helicene-bipyridine-rhenium complexes

Journal article published in 2015 by Nidal M. Saleh, Monika Srebro ORCID, Thibault Reynaldo, Nicolas Vanthuyne, Loïc Toupet, Victoria Y. Chang, Gilles Muller, J. A. Gareth Williams, J. A. Gareth Williams, Christian Roussel, Jochen Autschbach ORCID, Jeanne Crassous
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The incorporation of a rhenium atom within an extended helical π-conjugated bi-pyridine system impacts the chiroptical and photophysical properties of the resulting neutral or cationic complexes, leading to the first examples of rhenium-based phosphors that exhibit circularly polarized luminescence.