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Wiley, Angewandte Chemie International Edition, 34(50), p. 7807-7810, 2011

DOI: 10.1002/anie.201102544

Wiley, Angewandte Chemie, 34(123), p. 7953-7956, 2011

DOI: 10.1002/ange.201102544

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The Halogen Bond and Internal Dynamics in the Molecular Complex of CF3Cl and H2O

Journal article published in 2011 by Luca Evangelisti, Gang Feng, Patricia Écija, Emilio J. Cocinero ORCID, Fernando Castaño, Walther Caminati
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Molecular spinning tops: Five halogen-bonded isotopologues of the CF 3Cl-H 2O complex have been assigned by Fourier-transform microwave spectroscopy. All complexes are symmetric-top systems with evenly spaced bonds. The free internal rotation, relative stability, and structure of these complexes were determined (see picture; Ψ, θ, and φ: angles, a and b: axes of the monomer, and A: axis of the complex).