Published in
Royal Society of Chemistry, Chemical Communications, 79(50), p. 11721-11723, 2014
DOI: 10.1039/c4cc04277h
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The use of a well-defined surface organometallic complex as a probe molecule: [(SiO)TaVCl2Me2] shows different isolated silanol sites on the silica surface
Journal article published in 2014 by
Yin Chen,
Bin Zheng,
Edy Abou-Hamad,
Ali Hamieh,
Bilel Hamzaoui,
Kuo-Wei Huang 
,
Jean-Marie Basset
,
Jean-Marie Basset
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Abstract
Ta(V)Cl2Me3 reacts with silica(700) and produces two different [([triple bond, length as m-dash]SiO)Ta(V)Cl2Me2] surface organometallic species, suggesting a heterogeneity of the highly dehydroxylated silica surface, which was studied with a combined experimental and theoretical approach.