Oxidative Perhydroxylation of [closo-B12H12]2− to the Stable Inorganic Cluster Redox System [B12(OH)12]2−/.−: Experiment and Theory
Journal article published in 2010 by
Nguyen Van,
Ioannis Tiritiris,
Rainer F. Winter,
Biprajit Sarkar,
Priti Singh,
Carole Duboc 
,
Alvaro Muñoz-Castro,
Ramiro Arratia-Pérez,
Wolfgang Kaim,
Thomas Schleid
,
Alvaro Muñoz-Castro,
Ramiro Arratia-Pérez,
Wolfgang Kaim,
Thomas Schleid
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Abstract
The air stable, paramagnetic, sparingly water-soluble, solvent-free radical compound Cs[B12(OH)12] is synthesized in almost quantitative yield by perhydroxylation of Cs2[B12H12] with 30% H2O2 at 65 °C for six days.