Published in
American Chemical Society, Organic Process Research and Development, 6(16), p. 1230-1234
DOI: 10.1021/op300079z
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Selective Hydrogenation of Alkenes Under Ultramild Conditions
Journal article published in 2012 by
Valerica Pandarus,
Genevieve Gingras,
François Béland,
Rosaria Ciriminna,
Mario Pagliaro 
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Abstract
SiliaCat Pd0 solid catalyst heterogeneously mediates at room temperature the selective hydrogenation of a wide variety of alkenes under hydrogen balloon conditions using a modest 0.1 mol % catalyst amount. The catalyst is recyclable with negligible leaching of valued palladium, providing the chemical industry with a suitable replacement for less selective metal-based catalysts.