Published in

American Institute of Physics, Journal of Applied Physics, 7(93), p. 4276-4282, 2003

DOI: 10.1063/1.1556190

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Guided self-assembly of molecular dipoles on a substrate surface

Journal article published in 2003 by Y. F. Gao ORCID, Z. Suo
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

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Abstract

Molecules adsorbed on a substrate surface can self-assemble into a monolayer. This article models the process of self-assembly guided by an external object. The molecules are electric dipoles, diffusing on the surface at an elevated temperature. Pre-pattern a flat mask with a submonolayer of immobile atoms, which gives rise to a patterned contact potential field. Bring the mask to a small distance above the substrate. The electrostatic interaction transfers the pattern on the mask to a molecular pattern on the substrate. Similarly, one can place above the molecules a charged conducting tip, or a mask that is pre-patterned with a topographic surface. Our model includes the mobile molecular dipoles on the substrate surface, the guiding object, and the electrostatic field in the intervening space. A nonlinear diffusion equation simulates the pattern transfer process. Numerical results are presented when the guiding object is a flat metal, patterned with a submonolayer of immobile atoms. © 2003 American Institute of Physics.