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Wiley, Journal of Polymer Science Part A: Polymer Chemistry, 12(42), p. 2973-2984, 2004

DOI: 10.1002/pola.20134

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Side‐chain functionalized polymers containing bipyridine coordination sites: Polymerization and metal‐coordination studies

Journal article published in 2004 by Joseph R. Carlise, Marcus Weck ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Monomers containing (trisbipyridine) ruthenium(II), (bisbipyridine) palladium(II), and heteroleptic ruthenium complexes were synthesized and polymerized via ruthenium-catalyzed ring-opening metathesis polymerization in nonpolar solvents. The solubility of the resulting polyelectrolytes in nonpolar solutions could be tuned by alkyl functionalization of the ligands around the metal centers. These polymers are the first polynorbornenes containing a 2,2′-bipyridine-based metal complex at each repeating unit and might be used in numerous applications, including luminescent and electroluminescent materials. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2973–2984, 2004