Wiley, Angewandte Chemie, 16(121), p. 2938-2942, 2009
Wiley, Angewandte Chemie International Edition, 16(48), p. 2894-2898, 2009
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Just add it! Ruthenium initiators functionalized with hydrogen-bonding sites were utilized in ring-opening metathesis polymerization to prepare heterotelechelic polymers with hydrogen-bonding and metal-coordination units in a single step. Supramolecular ABC triblock copolymers were then self-assembled in one pot by simply adding complementary telechelic polymers to a solution of the heterotelechelic polymer (see picture).