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Wiley, Advanced Synthesis & Catalysis, 1(347), p. 161-171, 2005

DOI: 10.1002/adsc.200404264

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Evidence that SCS Pincer Pd(II) Complexes are only Precatalysts in Heck Catalysis and the Implications for Catalyst Recovery and Reuse

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This paper is available in a repository.

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Abstract

SCS-pincer Pd(II) complexes have been co- valently immobilized onto porous silica, cross-linked polymer (Merrifield resin) and soluble poly(norbor- nene) supports via either amide or urea linkages and evaluated in the Heck coupling of iodobenzene with n-butyl acrylate. Kinetic experiments and poi- soning studies indicate that in all cases the pincer complexes merely act as precatalysts. Contrary to lit- erature reports, there is no evidence for catalysis by the intact amide-linked SCS-Pd(II) complexes under any conditions studied here.