Published in
Royal Society of Chemistry, Chemical Communications, 15(50), p. 1906, 2014
DOI: 10.1039/c3cc48110g
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Nitronyl nitroxide-metal complexes as metallo-ligands for the construction of hetero-tri-spin (2p-3d-4f) chains
Journal article published in 2014 by
Mei Zhu,
Xuelan Mei,
Yue Ma,
Licun Li,
Dai-Zheng Liao,
Jean-Pascal Sutter 
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Abstract
A novel approach for the preparation of hetero-tri-spin magnetic compounds is described. It consists in using preformed metal-nitronyl nitroxide complexes as metallo-ligands in an assembling process involving an additional metal centre. This is illustrated by two unprecedented radical-Cu-Ln chain compounds (Ln = Gd3+, Tb3+).