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American Institute of Physics, Journal of Applied Physics, 12(101), p. 123911

DOI: 10.1063/1.2748723

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Magnetic properties and enhanced magnetic refrigeration in (Mn1-xFex)5Ge3 compounds

Journal article published in 2007 by Q. Zhang, J. Du ORCID, Y. B. Li, N. K. Sun, W. B. Cui, D. Li, Z. D. Zhang
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Magnetic and magnetocaloric effects of (Mn1-xFex)5Ge3 compounds are studied systematically. The maximum of magnetic entropy changes of 8.01 J/kg K under an external field change of 5 T is obtained for (Mn0.9Fe0.1)5Ge3, which is the largest value in Mn5Ge3-based solid solutions. Moreover, the Fe substitution increases the refrigeration capacity (RC) value greatly. The largest RC value of 237 J/kg in (Mn0.8Fe0.2)5Ge3 even compares favorably to that of many well-known magnetic refrigeration materials. Thus the Fe-containing (Mn1-xFex)5Ge3 compounds are much-improved magnetic refrigerants for the application of room-temperature magnetic refrigeration. The increase of the RC value is probably resulted from the formation of magnetic nanostructure.