In this paper, we present for the first time a proper-motion-selected white dwarf (WD) sample of the old Galactic open cluster M 67, down to the bottom of the WD cooling sequence (CS). The color-magnitude diagram is based on data collected with the LBC-Blue camera at the prime-focus of LBT. As first epoch data, we used CFHT-archive images collected 10 years before LBC data. We measured proper motions of all the identified sources. Proper motions are then used to separate foreground and background objects from the cluster stars, including WDs. Finally, the field-object cleaned WD CS in the V vs. B-I color-magnitude diagram is compared with the models. We confirm that the age derived from the location of the bottom of the WD CS is consistent with the turn off age. Based on data acquired using the Large Binocular Telescope (LBT) at Mt. Graham, Arizona, under the Commissioning of the Large Binocular Blue Camera. The LBT is an international collaboration among institutions in the United States, Italy and Germany. LBT Corporation partners are: The University of Arizona on behalf of the Arizona university system; Istituto Nazionale di Astrofisica, Italy; LBT Beteiligungsgesellschaft, Germany, representing the Max-Planck Society, the Astrophysical Institute Potsdam, and Heidelberg University; The Ohio State University, and The Research Corporation, on behalf of The University of Notre Dame, University of Minnesota and University of Virginia; and on observations obtained at the Canada-France-Hawaii Telescope (CFHT) which is operated by the National Research Council of Canada, the Institut National des Sciences de l'Univers of the Centre National de la Recherche Scientifique of France, and the University of Hawaii.Visiting PhD Student at STScI under the “2008 graduate research assistantship” program.