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Royal Society of Chemistry, Chemical Communications, 31(50), p. 4076-4078, 2014

DOI: 10.1039/c3cc49416k

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The corrole and ferrocene marriage: 5,10,15-triferrocenylcorrolato Cu

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Abstract

Two synthetic routes have been defined for the preparation of a 5,10,15-triferrocenylcorrole Cu derivative. This complex has been characterized and the preliminary electrochemical investigation shows a strong interaction among the corrole and meso ferrocenyl substituents. The results obtained suggest that peculiar properties are gained by combining the eccentric characteristics of ferrocenyl substitution with the corrole macrocycle.