Published in
Elsevier, Tetrahedron Letters, 35(54), p. 4712-4716
DOI: 10.1016/j.tetlet.2013.06.099
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Enhanced heterogeneously catalyzed Suzuki–Miyaura reaction over SiliaCat Pd(0)
Journal article published in 2013 by
Valerica Pandarus,
Delphine Desplantier-Giscard,
Genevieve Gingras,
Rosaria Ciriminna,
Piera Demma Cara,
François Béland,
Mario Pagliaro 
,
Piera Demma Cara'
,
Piera Demma Cara'
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Abstract
The SiliaCat Pd(0) solid catalyst can be efficiently employed in the Suzuki–Miyaura cross-coupling of an ample variety of haloarenes, including economically viable chloroarenes. The catalyst can be extensively recycled without loss of activity and with low leaching of valued palladium, opening the route to widespread utilization of the method to afford high yields of biaryls devoid of contaminating by-products.