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Hydrogen transfer hydrogenation of acetophenone by ruthenium complexes containing polydentate aminophosphine ligand

Journal article published in 1998 by 许翩翩, 高景星, 郑荣辉, 彭蔚萍, Pp-P. Xu, 黄培强, 万惠霖, 王文国, 丁开宁, 陈守正, Jx-X. Gao, Rh-H. Zheng, Wp-P. Peng, Pq-Q. Huang ORCID, Hl-L. Wan and other authors.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

The catalytic hydrogen transfer hydrogenation of acetophenone using C-2-symmetric diamine/diphosphine ruthenium(II) complex has been studied. Complex RuCl2(P2N2H4) shows an excellent catalytic activity in hydrogen transfer hydrogenation of acetophenone ina molar ratio-of substrate/Ru/iso-PrOK 200:1:12, leading to 2-phenylethanol in 99% yield after 2 h, A hydrogen transfer mechanism is also discussed.