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Thieme Gruppe, Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry, 04(2011), p. 565-568, 2011

DOI: 10.1055/s-0030-1259521

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Studies towards the Total Asymmetric Synthesis of the Pentacyclic Indole Alkaloid Arboflorine: Asymmetric Synthesis of a Key Intermediate

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The synthesis of a plausible key intermediate for a biomimetic asymmetric synthesis of indole alkaloid arboflorine is described. The method featured the use of Ellman's sulfinamide chemistry for the establishment of the first chiral center, and the Polonovski-Potier reaction for the formation of the alpha-aminonitrile moiety. ; NSF of China[20832005]; NFFTBS[J1030415]; National Basic Research Program (973 Program) of China[2010CB833200]