Published in
Royal Society of Chemistry, Chemical Science, 23(12), p. 8096-8104, 2021
DOI: 10.1039/d1sc01796a
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Synthesis, structure, and reactivity of uranium(vi) nitrides
Journal article published in 2021 by
Luciano Barluzzi,
Fang-Che Hsueh,
Rosario Scopelliti 
,
Benjamin E. Atkinson ,
Nikolas Kaltsoyannis ,
Marinella Mazzanti
,
Benjamin E. Atkinson ,
Nikolas Kaltsoyannis ,
Marinella Mazzanti
This paper is made freely available by the publisher.
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Abstract
The first examples of molecular compounds containing the cyclic (U(vi)N)2 and (U(v)U(vi)N)2 cores were obtained by oxidation of the (U(v)U(v)N)2 analogue. Different bonding within these complexes yields different stability and reactivity with CO and H2.