Published in

Wiley, Angewandte Chemie International Edition, 37(60), p. 20210-20214, 2021

DOI: 10.1002/anie.202106025

Links

Tools

Export citation

Search in Google Scholar

Catalytic Reduction of N<sub>2</sub> to Borylamine at a Molybdenum Complex

Journal article published in 2021 by Soukaina Bennaamane, Maria F. Espada, Andrea Mulas, Théo Personeni, Nathalie Saffon‐Merceron, Marie Fustier‐Boutignon, Christophe Bucher ORCID, Nicolas Mézailles ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

AbstractCatalytic formation of borylamines from atmospheric N2 is achieved for the first time using a series of homogenous (triphosphine)Mo complexes. Stepwise functionalization of the (triphosphine)Mo‐nitrido complex with chloroborane led to the synthesis of the imido complex. Electrochemical characterization of the (PPP)Mo‐nitrido and (PPP)Mo‐borylimido complexes showed that the latter is much more easily reduced.