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Wiley, Angewandte Chemie International Edition, 47(62), 2023

DOI: 10.1002/anie.202309501

Wiley, Angewandte Chemie, 47(135), 2023

DOI: 10.1002/ange.202309501

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Artificial Molecular Ratchets: Tools Enabling Endergonic Processes

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

AbstractNon‐equilibrium chemical systems underpin multiple domains of contemporary interest, including supramolecular chemistry, molecular machines, systems chemistry, prebiotic chemistry, and energy transduction. Experimental chemists are now pioneering the realization of artificial systems that can harvest energy away from equilibrium. In this tutorial Review, we provide an overview of artificial molecular ratchets: the chemical mechanisms enabling energy absorption from the environment. By focusing on the mechanism type—rather than the application domain or energy source—we offer a unifying picture of seemingly disparate phenomena, which we hope will foster progress in this fascinating domain of science.