Published in
Royal Society of Chemistry, Chemical Communications, 9(58), p. 1358-1361, 2022
DOI: 10.1039/d1cc06912h
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Iterative step-growth synthesis and degradation of unimolecular polyviologens under mild conditions
Journal article published in 2022 by
Abigail O. Delawder 
,
Mark S. Palmquist ,
Jovelt M. Dorsainvil ,
Nathan D. Colley ,
Tiana M. Saak ,
Max C. Gruschka ,
Xuesong Li ,
Lei Li ,
Yipei Zhang ,
Jonathan C. Barnes
,
Mark S. Palmquist ,
Jovelt M. Dorsainvil ,
Nathan D. Colley ,
Tiana M. Saak ,
Max C. Gruschka ,
Xuesong Li ,
Lei Li ,
Yipei Zhang ,
Jonathan C. Barnes
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Abstract
An iterative step-growth synthesis up to 26 viologen subunits is established for unimolecular polyviologens on a gram scale. Facile degradation of the polyviologens under mildly basic conditions was demonstrated in solution and in hydrogel networks.