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Wiley, European Journal of Organic Chemistry, 2023

DOI: 10.1002/ejoc.202300963

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Perfluoroalkylated Sulfoximines as Analogues of Togni Reagents: The Crucial Role of Fluorine Atoms for the Stability of Hypervalent Iodine Scaffolds

Journal article published in 2023 by Thibaut Duhail, Jorna Kalim ORCID, Jérôme Marrot ORCID, Bruce Pégot, Emmanuel Magnier ORCID, Elsa Anselmi ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

AbstractHypervalent iodine compounds are described with perfluoroalkyl chains and S‐perfluoromethyl sulfoximines as ligands of the halogen. The influence of these groups on the stability of the cyclic structure is studied. The crucial role of the trifluoromethyl chain is clearly highlighted as an efficient ligand for the hypervalency. The structure and the reactivity of the new skeletons are discussed in detail.