Published in
Royal Society of Chemistry, Chemical Science, 21(13), p. 6297-6302, 2022
DOI: 10.1039/d2sc01547a
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Dynamic kinetic resolution of transient hemiketals: a strategy for the desymmetrisation of prochiral oxetanols
Journal article published in 2022 by
Alexander Sandvoß 
,
Henning Maag,
Constantin G. Daniliuc ,
Dieter Schollmeyer,
Johannes M. Wahl
,
Henning Maag,
Constantin G. Daniliuc ,
Dieter Schollmeyer,
Johannes M. Wahl
This paper is made freely available by the publisher.
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Abstract
Desymmetrization of prochiral oxetanols via an electron-deficient hemiketal intermediate is achieved. Key to this process is the catalyst's chiral recognition of one of the two hemiketal enantiomers enabling an efficient dynamic kinetic resolution.