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Royal Society of Chemistry, Dalton Transactions, 20(50), p. 7078-7084, 2021

DOI: 10.1039/d1dt00765c

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Coordination capacity of Keggin anions as polytopic ligands: case study of [VNb12O40]15−

Journal article published in 2021 by Anna A. Mukhacheva ORCID, Victoria V. Volcheck ORCID, Dmitry G. Sheven ORCID, Vadim V. Yanshole ORCID, Nikolay B. Kompankov, Mohamed Haouas ORCID, Pavel A. Abramov ORCID, Maxim N. Sokolov ORCID
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Abstract

[VNb12O40]15− polytopic ligand can coordinate to up to five {(C6H6)Ru}2+ groups. Combined analytical separation tools together with 1H DOSY NMR were firstly applied to the solution studies of polyoxoniobate based complexes.