Published in
Royal Society of Chemistry, Organic Chemistry Frontiers, 2(9), p. 462-470, 2022
DOI: 10.1039/d1qo01480c
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Discovery of gargantulides B and C, new 52-membered macrolactones from Amycolatopsis sp. Complete absolute stereochemistry of the gargantulide family
Journal article published in 2022 by
Daniel Carretero-Molina,
Francisco Javier Ortiz-López 
,
Tetiana Gren ,
Daniel Oves-Costales,
Jesús Martín,
Fernando Román-Hurtado,
Tue Sparholt Jørgensen,
Mercedes de la Cruz,
Caridad Díaz,
Francisca Vicente,
Kai Blin,
Fernando Reyes ,
Tilmann Weber ,
Olga Genilloud
,
Tetiana Gren ,
Daniel Oves-Costales,
Jesús Martín,
Fernando Román-Hurtado,
Tue Sparholt Jørgensen,
Mercedes de la Cruz,
Caridad Díaz,
Francisca Vicente,
Kai Blin,
Fernando Reyes ,
Tilmann Weber ,
Olga Genilloud
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Abstract
Gargantulides B and C are among the most complex bacterial polyketides discovered so far. A combination of NMR and genome-based bioinformatics analyses allowed us to complete and revise the absolute stereochemistry of the entire gargantulide family.