Purpose The purpose of this paper is to develop a coated glass fiber fabric which can be used as the outer shell of firefighters' protective clothing and replace aramid fabric. Design/methodology/approach The silicone resin with excellent heat resistance was selected as the base solution. Silica nanoparticles, mica powder and ferric oxide were added into the coating solution, which was coated on the glass fiber fabrics. The vertical burning, thermal protective performance (TPP) value, second-degree burn time and water repellency of the coated fabrics were characterized. Findings Results showed that the dosages of the thickening filler were in the range 4%–6%; the coating solution has good viscosity. The optimal composition of fillers added in the silicone resin is silica nanoparticles 6%, ferric oxide 5% and mica powder 6%. The TPP value of the optimum coated fabric is 413 kW·s/m². The second-degree burn time is 4.98 s, which is obviously higher than that of the original glass fiber fabric (3.49 s) and that of the aramid fabric (3.82 s). The coated fabric has better thermal stability than aramid fabric. Originality/value The production cost of this coated glass fiber fabric was much lower than that of the aramid fabric.