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Royal Society of Chemistry, Chemical Communications, 81(56), p. 12242-12245, 2020

DOI: 10.1039/d0cc03357j

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Electroswitching of the single-molecule magnet behaviour in an octahedral spin crossover cobalt(ii) complex with a redox-active pyridinediimine ligand

Journal article published in 2020 by Renato Rabelo, Luminita Toma, Nicolás Moliner ORCID, Miguel Julve ORCID, Francesc Lloret ORCID, Jorge Pasán ORCID, Catalina Ruiz-Pérez ORCID, Rafael Ruiz-García, Joan Cano ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A unique example of electroswitchable spin crossover molecular nanomagnet which proceeds through one-electron oxidation of the slow-relaxing paramagnetic low-spin CoIIion (SCo= 1/2, ON) to the diamagnetic low-spin CoIIIion (SCo= 0, OFF).