Abstract. An accurate measurement of the optical properties of aerosol is critical for quantifying the effect of aerosol on climate. Uncertainties persist and results of measurements vary significantly. Biomass burning (BB) aerosol has been extensively studied through both field and laboratory environments for North American fuels to understand the changes in optical and chemical properties as a function of aging. There is a need for a wider sampling of fuels from different regions of the world for laboratory studies. This work represents the first such study of the optical and chemical properties of wood fuel samples commonly used for domestic purposes in east Africa. In general, combustion temperature or modified combustion efficiency (MCE) plays a major role in the optical properties of the emitted aerosol. For fuels combusted with MCE of 0.974±0.015, which is referred to as flaming-dominated combustion, the single-scattering albedo (SSA) values were in the range of 0.287 to 0.439, while for fuels combusted with MCE of 0.878±0.008, which is referred to as smoldering-dominated combustion, the SSA values were in the range of 0.66 to 0.769. There is a clear but very small dependence of SSA on fuel type. A significant increase in the scattering and extinction cross section (with no significant change in absorption cross section) was observed, indicating the occurrence of chemistry, even during dark aging for smoldering-dominated combustion. This fact cannot be explained by heterogeneous oxidation in the particle phase, and we hypothesize that secondary organic aerosol formation is potentially happening during dark aging. After 12 h of photochemical aging, BB aerosol becomes highly scattering with SSA values above 0.9, which can be attributed to oxidation in the chamber. Aging studies of aerosol from flaming-dominated combustion were inconclusive due to the very low aerosol number concentration. We also attempted to simulate polluted urban environments by injecting volatile organic compounds (VOCs) and BB aerosol into the chamber, but no distinct difference was observed when compared to photochemical aging in the absence of VOCs.