Published in
Royal Society of Chemistry, Chemical Communications, 68(56), p. 9850-9853, 2020
DOI: 10.1039/d0cc03634j
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Structural evidence for a reaction intermediate mimic in the active site of a sulfite dehydrogenase
Journal article published in 2020 by
Ahmed Djeghader 
,
Mélanie Rossotti,
Saleh Abdulkarim ,
Frédéric Biaso,
Guillaume Gerbaud ,
Wolfgang Nitschke ,
Barbara Schoepp-Cothenet ,
Tewfik Soulimane ,
Stephane Grimaldi
,
Mélanie Rossotti,
Saleh Abdulkarim ,
Frédéric Biaso,
Guillaume Gerbaud ,
Wolfgang Nitschke ,
Barbara Schoepp-Cothenet ,
Tewfik Soulimane ,
Stephane Grimaldi
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Abstract
We provide structural and spectroscopic evidence for a molybdenum–phosphate adduct mimicking a proposed reaction intermediate in the active site of a prokaryotic sulfite oxidizing enzyme.