Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 1(22), p. 129-135, 2020
DOI: 10.1039/c9cp05473a
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About the origin of the large Stokes shift in aminoalkyl substituted heptamethine cyanine dyes
Journal article published in 2020 by
Cristina Sissa 
,
Anna Painelli ,
Francesca Terenziani ,
Massimo Trotta ,
Roberta Ragni
,
Anna Painelli ,
Francesca Terenziani ,
Massimo Trotta ,
Roberta Ragni
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Abstract
Aminoalkyl substituted heptamethine cyanines show a large Stokes shift, ascribed to the geometry relaxation upon photoexcitation that drives the molecule from a distorted ground state structure to a planar and cyanine-like excited state.