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Royal Society of Chemistry, New Journal of Chemistry, 25(43), p. 9943-9952, 2019

DOI: 10.1039/c9nj01907c

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Niobium uptake by a [P8W48O184]40−macrocyclic polyanion

Journal article published in 2019 by Alexandra A. Shmakova, Victoria V. Volchek ORCID, Vadim Yanshole ORCID, Nikolay B. Kompankov, Nicolas P. Martin ORCID, May Nyman ORCID, Pavel A. Abramov ORCID, Maxim N. Sokolov ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Incorporation of Nb into the [P8W48O184]40−anionic macrocyclic cavitand leads to formation of new Nb–W POMs. Inclusion of up to five {NbO(H2O)}3+groups was observed. Solution speciation of the Nb-encapsulating macrocycles was studied by HPLC-ICP-AES and SAXS.