Published in
Taylor and Francis Group, Molecular Crystals and Liquid Crystals, 1(549), p. 19-28, 2011
DOI: 10.1080/15421406.2011.581121
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Preparation and single crystal structure of a dirhenium(I) complex of a bent-core mesogen
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Abstract
Dinuclear complexes of ReI are prepared by functionalising a symmetric, bent-core mesogen containing two imine groups. The resulting complex is characterised by single crystal X-ray diffraction and presents the expected geometry, but unfortunately the introduction of the two Re(CO)4 moieties suppresses the mesomorphism of the parent ligand