Published in
Royal Society of Chemistry, Dalton Transactions, 34(48), p. 12974-12985, 2019
DOI: 10.1039/c9dt02440a
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New light on an old debate: does the RCN–PtCl2 bond include any back-donation? RCN←PtCl2 backbonding vs. the IR νCN blue-shift dichotomy in organonitriles–platinum(ii) complexes. A thorough density functional theory – energy decomposition analysis study
Journal article published in 2019 by
Girolamo Casella 
,
Célia Fonseca Guerra ,
Silvia Carlotto ,
Paolo Sgarbossa,
Roberta Bertani,
Maurizio Casarin
,
Célia Fonseca Guerra ,
Silvia Carlotto ,
Paolo Sgarbossa,
Roberta Bertani,
Maurizio Casarin
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Abstract
Disentagling the RCN←PtII π back-donation vs. νCN blue-shift dichotomy in organonitrile-PtII complexes.