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Royal Society of Chemistry, Chemical Communications, 61(55), p. 9027-9030, 2019

DOI: 10.1039/c9cc04250d

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Short-range ordering in a battery electrode, the ‘cation-disordered’ rocksalt Li1.25Nb0.25Mn0.5O2

Journal article published in 2019 by Michael A. Jones ORCID, Philip J. Reeves ORCID, Ieuan D. Seymour ORCID, Matthew J. Cliffe ORCID, Siân E. Dutton ORCID, Clare P. Grey
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

We demonstrate short-range ordering in Li-ion battery material Li1.25Nb0.25Mn0.5O2, and identify its local structure and correlation length—which is sensitive to synthesis conditions and has important consequences for the material's electrochemistry.