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Royal Society of Chemistry, Chemical Communications, 29(55), p. 4266-4269, 2019

DOI: 10.1039/c9cc01920k

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Defect-rich fluorographene nanosheets for artificial N2 fixation under ambient conditions

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Defect-rich fluorographene behaves as a metal-free catalyst for the artificial conversion of N2 to NH3 at ambient conditions. In 0.1 M Na2SO4, it achieves a faradaic efficiency (FE) of 4.2% with an NH3 formation rate (RNH3) of 9.3 μg h−1 mgcat.−1 at −0.7 V vs. RHE, with strong long-term electrochemical durability.