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Royal Society of Chemistry, Physical Chemistry Chemical Physics

DOI: 10.1039/c8cp05332d

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Unimolecular Decomposition Kinetics of the Stabilised Criegee Intermediates CH2OO and CD2OO

Journal article published in 2018 by Daniel Stone ORCID, Kendrew Au, Samantha Sime, Diogo J. Medeiros ORCID, Mark Blitz ORCID, Paul W. Seakins ORCID, Zachary Decker ORCID, Leonid Sheps ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Decomposition kinetics of stabilised CH2OO and CD2OO Criegee intermediates have been investigated as a function of temperature (450–650 K) and pressure (2–350 Torr) using flash photolysis coupled with time-resolved cavity-enhanced broadband UV absorption spectroscopy.