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Luminescence from neptunyl(VI) species in solution.

Journal article published in 2007 by Catherine Talbot-Eeckelaers, Sj Pope, Cj Jones, Rj Taylor ORCID, Fr Livens, Roy Copping, Daniel Sykes, Aj Hynes, Stephen Faulkner, Iain May, Faulkner S; C Talbot Eeckelaers; S J. A. Pope; A J. Hynes; .
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

The luminescence from the neptunyl(VI) ion and its polyoxometallate complexes has been investigated in solution for the first time. Emission occurs in the near-IR and is quenched effectively by O-H oscillators in the hydrated ion. The polyoxometallate complexes exclude solvent from the neptunyl coordination sphere and have much more intense and longer-lived emission spectra. Copyright © 2007 American Chemical Society.