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Royal Society of Chemistry, Chemical Communications, 38(54), p. 4778-4781
DOI: 10.1039/c8cc01052h
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Conformational control over an aldehyde fragment by selective vibrational excitation of interchangeable remote antennas
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Abstract
We apply vibrational antennas (OH or NH2 group) to achieve unprecedented conformational control over the heavy aldehyde fragment in 2-formyl-2H-azirine, using selective vibrational excitations of the OH or NH2 stretching overtones and combination modes.